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(1R,2R,3S,5R)-(−)-Pinanediol / 1 G

Purity: 99 %
Synonym: PINANEDIOL; cis-alpha-Pinene glycol; (1R,2R,3S,5R)-2,6,6-Trimethylnorpinane-2,3-diol; (−)-2-Hydroxyisopinocampheol; [1R-(1α,2α,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol
Molecular Formula: C10H18O2
Molecular Weight: 170.25
SKU: MND-53278
CAS Number: 22422-34-0
MDL number: MFCD09955216
Note: Prices are for comparison only. Contact Sales for current pricing.
Packing size: 1 G  
30.94 EUR



Safety Information


Hazard Statements

H315
H319
H335

Precautionary Statements

P280
P264
P501
P305 + P351 + P338
P261
P271
P405
P302 + P352
P362 + P364
P403 + P233
P304 + P340
P321
P264 + P265
P319
P332 + P317
P337 + P317

Pictograms



Properties

Signal WordWarning
Flash Point (C)110 °C - closed cup
Flash Point (F)230.0 °F - closed cup
Boiling Point101-102 °C/1 mmHg (lit.)
Melting Point57-59 °C (lit.)

 Product Description

(1R,2R,3S,5R)-(−)-Pinanediol is a chiral diol derived from pinene. It is used as a chiral auxiliary in asymmetric synthesis and various organic reactions.

 

Application:

(1R,2R,3S,5R)-(−)-Pinanediol is employed in the synthesis of enantiomerically pure compounds, serving as a chiral auxiliary to induce stereochemistry in target molecules.

 

 

Articles:

- Organoboranes: LI. Convenient procedures for the recovery of pinanediol in asymmetric synthesis via one-carbon homologation of boronic esters

Publication Date: Available online 4 May 2001

Herbert C. Brown, Milind V. Rangaishenvi

https://doi.org/10.1016/0022-328X(88)87067-0

 

- Two efficient methods for the cleavage of pinanediol boronate esters yielding the free boronic acids

Publication Date: Available online 9 March 2001

Simon J. Coutts, Julian Adams, Dale Krolikowski, Roger J. Snow

https://doi.org/10.1016/S0040-4039(00)77040-7

 

- Asymmetric synthesis of alkylarylcarbinols via reaction of a chiral pinanediol alkylboronic ester with arylmethyl chlorides

Publication Date: Available online 14 April 1998

George W. Kabalka, Nan-Sheng Li, Su Yu

https://doi.org/10.1016/S0957-4166(97)00565-X